Amino Acids, Peptides and Proteins (SPR Amino Acids, by J. S. Davies

By J. S. Davies

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1969, 112, 609. lE4 G. Prota, G. Scherillo, F. Napolano, and R. A. Nicolaus, Cazzettn, 1968, 98, 495. 155 156 20 Amino-acids, Peptides, and Proteins Scheme 8 The effectiveness of histidine in this reaction is attributed to the formation of the sparingly soluble metal ion-imidazolylpyruvic acid complexes which are end-products. 1661 167 Amino-acids possessing a /I-hydroxy-group form cyclic carbinolamines whereas cysteine afforded the product containing a thiazolidine ring, The effects of divalent metals were investigated and the change of the equilibrium was again followed spectroscopically.

Wheeler and R. , 1969, 40, 1. 17* G. A. Brodskaya and V. A. Sharpatyi, Zhur. fiz. , 1969, 43, 2390. 179 G. A. Shagisultanova, L. A. Il’yukevich, and I. G. Sidorova, Khim. uysok. Energii, 1969, 3, 364. l S o G. K . Burk and G. Schoffa, Internat. J . , 1969, 1, 113. D. J. Whelan, J . Chem. , 1968, 49, 4734. lS2 R. Poupko, B. L. Silver, and A. Lowenstein, Chem. , 1968, 453. lR3 K. E. Wilzbach, J. Amer. Chem. , 1957, 79, 1013. lS4 E. A. Evans, ‘Tritium and its Compounds’, Butterworths, London, 1966, p.

A7 91 98 93 94 g5 M. M. Shemyakin, Pure AppZ. , 1968, 17, 313. E. Lederer, Pure Appl. , 1968, 17, 489. G. VanLear and F. W. McLafferty, Ann. Rev. , 1969, 38, 289. M. M. Shemyakin, Yu. A. Ovchinnikov, E. I. Vinogradova, A. A. Kiryushkin, M. Yu. Feigina, N. A. Aldonova, Yu. B. Alakhov, V. M. Lipkin, A. I. Miroshnikov, B. V. Rosinov, and S. A. S. Letters, 1970, 7, 8. D. F. Hunt, C. E. Hignite, and K. Biemann, Biochem. Biophys. Res. , 1968, 33, 378. D. W. Thomas, E. Lederer, M. Bodanszky, J. Izdebski, and I.

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