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Additional resources for Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC)) (Vol 2)
1969, 112, 609. lE4 G. Prota, G. Scherillo, F. Napolano, and R. A. Nicolaus, Cazzettn, 1968, 98, 495. 155 156 20 Amino-acids, Peptides, and Proteins Scheme 8 The effectiveness of histidine in this reaction is attributed to the formation of the sparingly soluble metal ion-imidazolylpyruvic acid complexes which are end-products. 1661 167 Amino-acids possessing a /I-hydroxy-group form cyclic carbinolamines whereas cysteine afforded the product containing a thiazolidine ring, The effects of divalent metals were investigated and the change of the equilibrium was again followed spectroscopically.
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